Chemistry:2012:CBSE:[Delhi]:Set-III

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  • Q1

    What is meant by ‘doping’ in a semiconductor?

    Marks:1
    Answer:

    It is the process of increasing conductivity of the intrinsic semiconductors by adding suitable impurity.

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  • Q2

    What is the role of graphite in the electrometallurgy of aluminium?

    Marks:1
    Answer:

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  • Q3

    Out of PH3 and H2S which is more acidic and why?

    Marks:1
    Answer:

    Proton (H+) donors are acids. H2S is more acidic than PH3 because 

    sulphur is more electronegative than phosphorus. So, S-H bond is more polar than P-H bond resulting in easier removal of H+ ion.

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  • Q4

    Give the IUPAC name of the following compound.


    Marks:1
    Answer:

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  • Q5

    Draw the structure of hex-1-en-3-ol compound.

    Marks:1
    Answer:

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  • Q6

    Define the term, ‘homopolymerisation’ giving an example.

    Marks:1
    Answer:

    The addition polymers which are formed by the polymerisation of one type of monomeric species are known as homopolymers and the process is known as homopolymerisation.

    Example: Formation of polyethene (homopolymer of ethene)

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  • Q7

    Arrange the following in the decreasing order of their basic strength in aqueous solutions:

    CH3NH2, (CH3)2NH, (CH3)3N and NH3

    Marks:1
    Answer:

    Decreasing order of basic strength

    (CH3)2NH > CH3NH2 > (CH3)3N > NH3

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  • Q8

    Arrange the following compounds in an increasing order of their reactivity in nucleophilic addition reactions: ethanal, propanal, propanone, butanone.

    Marks:1
    Answer:

    Incresing order of reactivity:

    butanone < propanone < propanal < ethanal

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  • Q9

    A 1.00 molal aqueous solution of trichloroacetic acid (CCl3COOH) is heated to its boiling point. The solution has the boiling point of 100.18°C. Determine the van’t Hoff factor for trichloroacetic acid. (Kb for water= 0.512 kg mol-1)

    Marks:2
    Answer:

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  • Q10

    Define the following terms:

    (i) Mole fraction

    (ii) Isotonic solutions

    (iii) van’t Hoff factor

    (iv) Ideal solution

    Marks:2
    Answer:

    (i) Mole fraction:- It is the ratio of number of moles of one component (solute or solvent) to the total number of moles (solutes and solvent) present in a solution.

    (ii) Isotonic solutions :- They are those solutions which have same osmotic pressure at same temperature.

    (iii) van’t Hoff factor :- It is defined as the ratio of observed value of colligative property to the calculated value of colligative property. It is used to find out the extent of association or dissociation.

     (iv) Ideal solution:­-The solutions which obey Raoult’s law over the entire range of concentration is known as ideal solution.

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